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Phenolic-bonded Materials CAFS Research
Area 2 is devoted to the extensive study of brake materials
for automotive, heavy duty, and railroad applications. These
materials are usually fabricated from a large variety of
components and held together with phenolic resin
matrix.
Friction Materials for
Automotive Brakes The purpose of any transportation
brake system is to convert the kinetic and potential energies
of the vehicle into heat within the sliding interface. This
system is the number one safety feature of any
vehicle.
A brake system consists of two
components: 1. actuating system (hydraulic or
pneumatic) 2. frictional system (lining or pad, disc or
drum)
Disc Brake
Drum
Brake
Historical Development of Automotive Brake
Materials • Wood (blocks, leather lining in spoon
brakes, band type brakes) • Metal to metal (iron shoes
against steel • earliest drum stoppers Renault 1903) •
Asbestos reinforced with brass (Frood 1908) • Sintered
iron, copper, brass • Semi-metallics (polymer matrix –
phenolics) • Non-metallic • Hybrid (compromising) •
Ceramic (C/C, C/SiC, C/BN, C/B4C)
(2000)
Trends • Higher performance (larger
energies dissipated in smaller friction systems; cost, weight
and size of braking systems reduced, a more efficient stopping
system)
• The coefficient of friction • Wear rate •
Environmental load • Noise and vibration • Chemical
species
•
Higher stability and reliability (US federal requirement,
reduced need for maintenance and repair) • Shift from trial
and error design to science- understanding of principles •
Environmental requirements and limitations
Current
Formulation Philosophy The current formulation
philosophy is that low-cost, environmentally-friendly brake
materials can be made with good physical properties, adequate
and stable friction in a wide range of operating conditions,
minimal fade, and high resistance to wear and compatibility
with its rubbing counterpart.
Brake Properties and
Their Relevance

Disc
and Drum Materials Grey Cast Iron for Rotors and
Discs
Cast Iron Chemistry and Hardness • 2.8 –
3.2 wt.% C • 1.6 – 1.9 wt.% Si • 0.6 – 0.8 wt.% Mn •
a maximum of 0.15 wt. % S • a maximum of 0.3 wt.% P •
CEV = total C % + (P % + Si %)/3 = 3.8 - 3.9 % • Additional
elements possible (carbides, Ti, Cr, Ni) • HB = 170 –
280 Brake Linings • Polymer Matrix Composites •
Sintered Metallics • Ceramics
Brake Lining
Materials At the Center for Advanced Friction Studies,
we have examined and tested more than 3000 different
materials. A brake lining typically contains 10 to 30
different materials. We have categorized these by the role of
the component in the material. These components
include:
•
Binders • Reinforcements • Friction modifiers •
Fillers
|
Matrix
(Binder) |
Fibers & Particulates |
Friction Modifier
-
Lubricant |
Friction Modifier
-
Abrasive |
Volume
Filler |
|
Novolac |
Metallic |
Graphite |
SiC |
Barites |
|
Cresol |
Polymeric |
Coke |
Al2O3 |
CaO |
|
Cashew Resin |
Mineral Ceramics |
MoS2 |
ZrSiO4 |
CaCO3 |
|
Rubber |
Glass |
Titanates |
SiO3 |
MgO |
|
Polyimid |
|
Sulfates |
Cr2O3 or FeO |
|
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Polyester |
|
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WC |
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